科学研究 情况简介 |
1.主要研究方向 （1）离子液体在有机合成中的应用； （2）医药中间体的合成； （3）量子化学计算。 2.承担项目 （1）广东省自然科学基金项目、，2018A030307022，离子液体中脂肪酶催化的Michael加成反应，2018/05-2021/04，10.0万元，在研，主持。 （2）广东省普通高校特色创新项目，2018KTSCX126，离子液体中脂肪酶催化的不对称Aldol反应，2019/01-2020/12，5.0万元，在研，主持。 （3）衢州福瑞凯化工科技有限公司科研计划项目（横向课题）、索菲布韦关键中间体五氟酚（五氟苯酚）的合成工艺开发、2015/11-2018/10、20.0万元、结题、主持。 3.代表论文 (1) Yun Wang*,Xin-Yi Chen, Xin-Yi Liang, Zhi-Hui Liang, Hong Cheng, Xiang Li, Li-Ling Li.Pepsin‑Catalyzed Asymmetric Cross Aldol Reaction Promoted by Ionic Liquids and Deep Eutectic Solvents. Catalysis Letter, 2020, 150: 2549~2557. (2)Yun Wang*,Xin-Yi Liang, Xin-Yi Chen, Zhi-Hui Liang, Hong Cheng, Xiang Li, Li-Ling Li. Promotion of water in BPL-catalyzed asymmetric cross aldol reaction. Biomass Conversion and Biorefinery, 2020, published online, doi: 10.1007/s13399-020-00695-0. (3)Yun Wang*,Hong Cheng, Xiang Li, Li-Ling Li, Zhi-Hui Liang, Xin-Yi Liang, Xin-Yi Chen.MML-catalyzed direct aldol reaction in green solvents. Biomass Conversion and Biorefinery, 2020, published online, doi: 10.1007/s13399-020-00953-1. (4) Rong-Kai Pan,Yun Wang*, Jiang-Li Song, Sheng-Gui Liu. Two cadmium(II) complexes derived from bidentatebis(benzoimidazol-2- ylmethyl) cyclohexane ligands: synthesis, crystal structures, spectroscopic and DFT calculations. Chemical paper, 2018,72: 2181-2191. (5)Xiumei Song, Fuling Xue, Zongcai Feng,Yun Wang*, Zhaoyang Wang, Yanli Xi. A Combined Experimental and Theoretical Study on the Reaction Mechanism and Molecular Structure of 4-(Diphenylamino)-3- iodo-2(5H)-furanon. Australian Journal of Chemistry, 2017,70, 837-844. (6)Yun Wang*. An Experimental and Theoretical Study on the Preparation of 4,4’-methylene-bis(N, N-dimethylaniline) in Ionic liquid. Journal of Physical Organic Chemistry, 2016, 29:276 ~280. |
