科学研究 情况简介 | 1. 主要研究方向 硫化学、绿色化学、有机合成催化、不对称催化 2. 承担项目 (1) 国家自然科学基金委员会, 青年科学基金项目, 22101106, 新型硫亚胺阴离子前体的设计合成及其在偶联反应中的应用, 2022年1月 至 2024年12月, 30万元, 在研, 主持； (2) 岭南师范学院人才引进基金，ZL2021026，可回收铑催化剂的设计合成及应用，2021年1月至2025年12月，10万元，在研，主持； (3) 国家自然科学基金委员会, 青年科学基金项目, 21602067, 新型双官能碘盐催化剂的设计合成及其在不对称绿色氧化反应中的应用, 2017年1月 至 2019年12月,20万元, 结题, 参与； (4) 华中科技大学创新研究院项目，2018JYCXJJ042，纳米反应器催化脂肪胺的绿色合成研究， 2018年1月至2019年12月，5万元，结题，主持。
3. 论文和专利 独立工作后： 1. Guoling Huang, Xunbo Lu*, Kaiyuan Yang, Xinyu Xu. "Redox-Neutral Synthesis of Sulfilimines through the S-Alkylation of Sulfenamides" Org. Lett. 2023, 25, 3173. (独立通讯作者) Also published as a preprint: ChemRxiv, 2023, DOI: 10.26434/chemrxiv-2023-253pv. 2. Guoling Huang, Xunbo Lu*, Fanpeng, Liang. "Redox-Neutral Strategy for Sulfilimines Synthesis via S-Arylation of Sulfenamides." Org. Lett. 2023, 25, 3179. (独立通讯作者) Also published as a preprint: ChemRxiv, 2023, DOI: 10.26434/chemrxiv-2023-2frs3. 3. Xunbo Lu*, Guoling Huang, Jianlin Ye, et al. "Hypervalent Iodine-mediated Synthesis of Sulfinimidate Esters from Sulfenamides." Org. Lett. 2023, 25, 2151. (独立通讯作者) 4. Xunbo Lu*, Guoling Huang, Fanpeng, Liang, et al. "A Highly Efficient Method to Access Unprotected C-3 Bifunctional Quaternary 3-Allyl-3-(amino)oxindoles." Org. Biomol. Chem., 2023, 21, 3547. (独立通讯作者) 5. Xunbo Lu*, Kaiyuan Yang, Xinyu Xu, et al. "Rh(II)-Catalyzed Doyle–Kirmse Reaction: Access to Unprotected 3-Allyl/3-allenyl-3-(thio)oxindoles." Org. Biomol. Chem., 2022, 20, 9228. (独立通讯作者) 6. Guoling Huang, Jianlin Ye, Yuetong Chen, Minxi Tan. Xunbo Lu*, "Cu(II)-Catalyzed Aerobic Synthesis of Sulfinamidines from Sulfenamides." J. Org. Chem. (Under Review). (独立通讯作者) Also published as a preprint: ChemRxiv, 2023, DOI:10.26434/chemrxiv-2023-31393. 7. Guoling Huang, Jianlin Ye, Muhammad Adnan Bashir, Yuetong Chen, Wenjing Chen. Xunbo Lu*,"Expanding the Scope of Hypervalent Iodine Reagents in the Synthesis of Sulfinamides from Sulfenamides. " J. Org. Chem. (Accepted). (独立通讯作者) Also published as a preprint: ChemRxiv, 2023, DOI:10.26434/chemrxiv-2023-b0d6x. 8. 一种硫亚胺酯\酰胺的制备方法.卢训博，黄国玲. CN202211620526.0 (公开). 9. 一种芳基硫亚胺类化合物的制备方法：卢训博，黄国玲. 10. 一种非氧化制备硫亚胺类化合物的方法：卢训博，黄国玲.
独立工作前： (1) Xunbo Lu, Yulong Bai, Jingyang Qin, Nan Wang, Yuzhou Wu, Fangrui Zhong*. "Alleviating catalyst decay enables efficient intermolecular C(sp3)–H amination under mechanochemical conditions. " ACS Sustain.Chem. Eng., 2021, 9, 1684. (2) Xunbo Lu, Yulong Bai, Yan Li, Yufeng Shi, Longjie Li, Yuzhou Wu, Fangrui Zhong*. "Assembly of C3a-Peroxylated Pyrroloindolines via Interrupted Witkop Oxidation." Org. Lett., 2018, 20, 7937. (3) Xunbo Lu, Yufeng Shi, Fangrui Zhong*. "Rhodium-Catalyzed Intermolecular C(sp3)–H Amination in a Purely Aqueous System." Green Chem., 2018, 20, 113. (4) Dangui Wang, Wentao Zhang, Xunbo Lu, Hongwei Zhou*, Fangrui Zhong*. "Cinchona Alkaloid Derived Iodide Catalyzed Enantioselective Oxidative α-Amination of Carbonyl Compounds toward the Construction of Spiroindolyloxindole." Org. Lett., 2022, 24, 842. (5) Dangui Wang, Xunbo Lu, Shaohan Sun, Huaibin Yu, Huimin Su, Yuzhou Wu, Fangrui Zhong* "Unified and Benign Synthesis of Spirooxindoles via Bifunctional and Recyclable Iodide‐Salt‐Catalyzed Oxidative Coupling in Water. " Eur. J. Org. Chem. 2019, 35, 6028. (6) Muhammad Adnan Bashir, Honghua Zuo, Xunbo Lu, Yuzhou Wu, Fangrui Zhong*. "Harnessing structurally unbiased ortho-benzoquinone monoimine for biomimetic oxidative [4+2] cycloaddition with enamines. " Chem. Commun., 2020, 56, 5965. (7) Yan Li, Juan Guo, Xunbo Lu, Fangrui Zhong.* "One-Step Assembly of Alkoxypyrroloindolines via Iodine-Catalyzed Alkoxycyclization of Indole Derivatives." Org. Biomol. Chem., 2020, 18, 32. (8) Yufeng Shi, Yufan Wang, Xunbo Lu, Yulong Zhang, Yuzhou Wu, Fangrui Zhong.* "Rhodium-Catalyzed Aminohydroxylation of Unactivated Alkenes in Aqueous Media for the Benign Synthesis of 1,2-Amino Alcohols" Green Chem., 2019, 21, 780. (9) Yan Li, Longjie Li, Xunbo Lu, Yulong Bai, Yufan Wang, Yuzhou Wu, Fangrui Zhong*. "Bioinspired Radical Cyclization of Tryptamines: Synthesis of Peroxypyrroloindolenines as Potential Anti-Cancer Agents." Chem. Commun., 2019, 55, 63. (10) 一种苯并呋喃并吲哚类化合物、其制备和应用. 钟芳锐，张玉龙，卢训博，吴钰周. (授权号：CN111303171B). (11) 一种机械力促进的脂肪胺制备方法. 钟芳锐，卢训博，吴钰周，张玉龙，白玉龙，汪雨凡. (授权号：CN108440344B). (12) 一种一锅法制备1,2-氨基醇类化合物的方法. 钟芳锐，汪雨凡，白玉龙，卢训博，张玉龙. (授权号: CN108484451B). (13) 一种过氧取代的吡咯/呋喃并吲哚啉的制备方法. 钟芳锐，卢训博，白玉龙. (授权号： CN108484610B).
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